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Thus a prism of 1 Δ would produce 1 cm visible displacement at 100 cm, or 1 meter. This can be represented mathematically as: = where is the amount of prism correction in prism dioptres, and is the angle of deviation of the light.
Edwards equation. The Edwards equation in organic chemistry is a two-parameter equation for correlating nucleophilic reactivity, as defined by relative rate constants, with the basicity of the nucleophile (relative to protons) and its polarizability. This equation was first developed by John O. Edwards in 1954 [1] and later revised based on ...
Esophoria is an eye condition involving inward deviation of the eye, usually due to extra-ocular muscle imbalance. It is a type of heterophoria. Cause. Causes include: Refractive errors; Divergence insufficiency; Convergence excess; this can be due to nerve, muscle, congenital or mechanical anomalies.
Using the same chemical equation again, write the corresponding matrix equation: s 1 CH 4 + s 2 O 2 s 3 CO 2 + s 4 H 2 O {\displaystyle {\ce {{\mathit {s}}_{1}{CH4}+{\mathit {s}}_{2}{O2}->{\mathit {s}}_{3}{CO2}+{\mathit {s}}_{4}{H2O}}}}
Marcus theory is used to describe a number of important processes in chemistry and biology, including photosynthesis, corrosion, certain types of chemiluminescence, charge separation in some types of solar cells and more. Besides the inner and outer sphere applications, Marcus theory has been extended to address heterogeneous electron transfer .
In quantum mechanics, perturbation theory is a set of approximation schemes directly related to mathematical perturbation for describing a complicated quantum system in terms of a simpler one. The idea is to start with a simple system for which a mathematical solution is known, and add an additional "perturbing" Hamiltonian representing a weak ...
One can put this equation in the following form: ln k T = − Δ H ‡ R ⋅ 1 T + ln κ k B h + Δ S ‡ R {\displaystyle \ln {\frac {k}{T}}={\frac {-\Delta H^{\ddagger }}{R}}\cdot {\frac {1}{T}}+\ln {\frac {\kappa k_{\mathrm {B} }}{h}}+{\frac {\Delta S^{\ddagger }}{R}}}
For a system undergoing a reversible reaction described by the general chemical equation α A + β B + ⋯ ⇌ ρ R + σ S + ⋯ {\displaystyle \alpha \,\mathrm {A} +\beta \,\mathrm {B} +\cdots \rightleftharpoons \rho \,\mathrm {R} +\sigma \,\mathrm {S} +\cdots }
Gibbs isotherm. The Gibbs adsorption isotherm for multicomponent systems is an equation used to relate the changes in concentration of a component in contact with a surface with changes in the surface tension, which results in a corresponding change in surface energy.
The formula for Volume Correction Factor is commonly defined as: V C F = C T L = exp { − α T Δ T [ 1 + 0.8 α T ( Δ T + δ T ) ] } {\displaystyle VCF=C_{TL}=\exp\{-\alpha _{T}\Delta T[1+0.8\alpha _{T}(\Delta T+\delta _{T})]\}}