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Perturbation theory (quantum mechanics) In quantum mechanics, perturbation theory is a set of approximation schemes directly related to mathematical perturbation for describing a complicated quantum system in terms of a simpler one. The idea is to start with a simple system for which a mathematical solution is known, and add an additional ...
Relativistic quantum chemistry. Relativistic quantum chemistry combines relativistic mechanics with quantum chemistry to calculate elemental properties and structure, especially for the heavier elements of the periodic table. A prominent example is an explanation for the color of gold: due to relativistic effects, it is not silvery like most ...
Fine structure. Interference fringes, showing fine structure (splitting) of a cooled deuterium source, viewed through a Fabry–Pérot interferometer. In atomic physics, the fine structure describes the splitting of the spectral lines of atoms due to electron spin and relativistic corrections to the non-relativistic Schrödinger equation.
Surface plasmon resonance ( SPR) is a phenomenon that occurs where electrons in a thin metal sheet become excited by light that is directed to the sheet with a particular angle of incidence, and then travel parallel to the sheet. Assuming a constant light source wavelength and that the metal sheet is thin, the angle of incidence that triggers ...
In quantum mechanics, an energy level is degenerate if it corresponds to two or more different measurable states of a quantum system. Conversely, two or more different states of a quantum mechanical system are said to be degenerate if they give the same value of energy upon measurement. The number of different states corresponding to a ...
Introduction to the concept. Quantum tunnelling falls under the domain of quantum mechanics. To understand the phenomenon, particles attempting to travel across a potential barrier can be compared to a ball trying to roll over a hill. Quantum mechanics and classical mechanics differ in their treatment of this scenario.
Dispersion (optics) In a dispersive prism, material dispersion (a wavelength -dependent refractive index) causes different colors to refract at different angles, splitting white light into a spectrum. In optics and in wave propagation in general, dispersion is the phenomenon in which the phase velocity of a wave depends on its frequency; [1 ...
Prism dioptres. Prism correction is commonly specified in prism dioptres, a unit of angular measurement that is loosely related to the dioptre. Prism dioptres are represented by the Greek symbol delta (Δ) in superscript. A prism of power 1 Δ would produce 1 unit of displacement for an object held 100 units from the prism. [2]
Unit cell with water molecules, used to simulate flowing water. Periodic boundary conditions (PBCs) are a set of boundary conditions which are often chosen for approximating a large (infinite) system by using a small part called a unit cell. PBCs are often used in computer simulations and mathematical models. The topology of two-dimensional PBC ...
The wavelength of light is then selected by the slit on the upper right corner. An optical spectrometer ( spectrophotometer, spectrograph or spectroscope) is an instrument used to measure properties of light over a specific portion of the electromagnetic spectrum, typically used in spectroscopic analysis to identify materials. [1]