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In quantum mechanics, perturbation theory is a set of approximation schemes directly related to mathematical perturbation for describing a complicated quantum system in terms of a simpler one. The idea is to start with a simple system for which a mathematical solution is known, and add an additional "perturbing" Hamiltonian representing a weak disturbance to the system. If the disturbance is ...
In particle physics, quantum electrodynamics ( QED) is the relativistic quantum field theory of electrodynamics. [1] [2] [3] In essence, it describes how light and matter interact and is the first theory where full agreement between quantum mechanics and special relativity is achieved. [2] QED mathematically describes all phenomena involving electrically charged particles interacting by means ...
A fundamental physical constant occurring in quantum mechanics is the Planck constant, h. A common abbreviation is ħ = h/2π, also known as the reduced Planck constant or Dirac constant .
Experimental electron energy loss spectrum, showing the major features: zero-loss peak, plasmon peaks and core loss edge. Electron energy loss spectroscopy ( EELS) is a form of electron microscopy in which a material is exposed to a beam of electrons with a known, narrow range of kinetic energies. Some of the electrons will undergo inelastic ...
The GW approximation (GWA) is an approximation made in order to calculate the self-energy of a many-body system of electrons. [1] [2] [3] The approximation is that the expansion of the self-energy Σ in terms of the single particle Green's function G and the screened Coulomb interaction W (in units of ) can be truncated after the first term:
In physics, relativistic quantum mechanics ( RQM) is any Poincaré covariant formulation of quantum mechanics (QM). This theory is applicable to massive particles propagating at all velocities up to those comparable to the speed of light c, and can accommodate massless particles. The theory has application in high energy physics, [1] particle ...
In physics, screening is the damping of electric fields caused by the presence of mobile charge carriers. It is an important part of the behavior of charge-carrying fluids, such as ionized gases (classical plasmas ), electrolytes, and charge carriers in electronic conductors ( semiconductors, metals ). In a fluid, with a given permittivity ε ...
Introductory courses on physics or chemistry typically introduce the Schrödinger equation in a way that can be appreciated knowing only the concepts and notations of basic calculus, particularly derivatives with respect to space and time. A special case of the Schrödinger equation that admits a statement in those terms is the position-space Schrödinger equation for a single nonrelativistic ...
Surface plasmon resonance. Surface plasmon resonance ( SPR) is a phenomenon that occurs where electrons in a thin metal sheet become excited by light that is directed to the sheet with a particular angle of incidence, and then travel parallel to the sheet. Assuming a constant light source wavelength and that the metal sheet is thin, the angle ...
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibria .