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Thus a prism of 1 Δ would produce 1 cm visible displacement at 100 cm, or 1 meter. This can be represented mathematically as: = where is the amount of prism correction in prism dioptres, and is the angle of deviation of the light.
The Scherrer equation, in X-ray diffraction and crystallography, is a formula that relates the size of sub-micrometre crystallites in a solid to the broadening of a peak in a diffraction pattern. It is often referred to, incorrectly, as a formula for particle size measurement or analysis.
The formula for Volume Correction Factor is commonly defined as: V C F = C T L = exp { − α T Δ T [ 1 + 0.8 α T ( Δ T + δ T ) ] } {\displaystyle VCF=C_{TL}=\exp\{-\alpha _{T}\Delta T[1+0.8\alpha _{T}(\Delta T+\delta _{T})]\}}
Incomitant strabismus cannot be fully corrected by prism glasses, because the eyes would require different degrees of prismatic correction dependent on the direction of the gaze. Incomitant strabismus of the eso- or exo-type are classified as "alphabet patterns": they are denoted as A- or V- or more rarely λ -, Y- or X-pattern depending on the ...
In stereochemistry, enantiomeric excess ( ee) is a measurement of purity used for chiral substances. It reflects the degree to which a sample contains one enantiomer in greater amounts than the other. A racemic mixture has an ee of 0%, while a single completely pure enantiomer has an ee of 100%. A sample with 70% of one enantiomer and 30% of ...
Compressibility factor values are usually obtained by calculation from equations of state (EOS), such as the virial equation which take compound-specific empirical constants as input.
This approach is also referred to as the Bennett-Chandler approach, which yields a dynamical correction to the standard transition state theory-based rate constant. It can be rewritten as: [2] k = κ k B T h e Δ S ‡ R e − Δ H ‡ R T {\displaystyle k={\frac {\kappa k_{\mathrm {B} }T}{h}}e^{\frac {\Delta S^{\ddagger }}{R}}e^{-{\frac ...
Surface plasmon resonance ( SPR) is a phenomenon that occurs where electrons in a thin metal sheet become excited by light that is directed to the sheet with a particular angle of incidence, and then travel parallel to the sheet. Assuming a constant light source wavelength and that the metal sheet is thin, the angle of incidence that triggers ...
Use of Møller–Plesset perturbation methods. Second (MP2), [3] third (MP3), [4] [5] and fourth (MP4) [6] order Møller–Plesset calculations are standard levels used in calculating small systems and are implemented in many computational chemistry codes.
Hammett equation. In organic chemistry, the Hammett equation describes a linear free-energy relationship relating reaction rates and equilibrium constants for many reactions involving benzoic acid derivatives with meta- and para- substituents to each other with just two parameters: a substituent constant and a reaction constant.