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The Benesi–Hildebrand method is a mathematical approach used in physical chemistry for the determination of the equilibrium constant K and stoichiometry of non-bonding interactions. This method has been typically applied to reaction equilibria that form one-to-one complexes, such as charge-transfer complexes and host–guest molecular ...
Prism dioptres. Prism correction is commonly specified in prism dioptres, a unit of angular measurement that is loosely related to the dioptre. Prism dioptres are represented by the Greek symbol delta (Δ) in superscript. A prism of power 1 Δ would produce 1 unit of displacement for an object held 100 units from the prism. [2]
Relativistic corrections (Dirac) to the energy levels of a hydrogen atom from Bohr's model. The fine structure correction predicts that the Lyman-alpha line (emitted in a transition from n = 2 to n = 1) must split into a doublet. The total effect can also be obtained by using the Dirac equation. In this case, the electron is treated as non ...
Heterophoria is the misalignment of the visual axis such that one or both eyes are not properly fixated to an object of interest. When the visual axis is misaligned in such a way, it is corrected by the fusional vergence system. Diagnosis. The cross-cover test, or alternating cover test is usually employed to detect heterophoria.
Exophoria. Exophoria is a form of heterophoria in which there is a tendency of the eyes to deviate outward. [1] During examination, when the eyes are dissociated, the visual axes will appear to diverge away from one another. [2] The axis deviation in exophoria is usually mild compared with that of exotropia .
Eyring equation. The Eyring equation (occasionally also known as Eyring–Polanyi equation) is an equation used in chemical kinetics to describe changes in the rate of a chemical reaction against temperature. It was developed almost simultaneously in 1935 by Henry Eyring, Meredith Gwynne Evans and Michael Polanyi.
The Tolman length is thus defined as the leading order correction in an expansion in /. The equimolar radius is defined so that the superficial density is zero, i.e., it is defined by imagining a sharp mathematical dividing surface with a uniform internal and external density, but where the total mass of the pure fluid is exactly equal to the ...
Marcus theory is used to describe a number of important processes in chemistry and biology, including photosynthesis, corrosion, certain types of chemiluminescence, charge separation in some types of solar cells and more. Besides the inner and outer sphere applications, Marcus theory has been extended to address heterogeneous electron transfer .
The Bohr–Sommerfeld model (also known as the Sommerfeld model or Bohr–Sommerfeld theory) was an extension of the Bohr model to allow elliptical orbits of electrons around an atomic nucleus. Bohr–Sommerfeld theory is named after Danish physicist Niels Bohr and German physicist Arnold Sommerfeld. Sommerfeld argued that if electronic orbits ...
The Schottky effect or field enhanced thermionic emission is a phenomenon in condensed matter physics named after Walter H. Schottky. In electron emission devices, especially electron guns, the thermionic electron emitter will be biased negative relative to its surroundings. This creates an electric field of magnitude F at the emitter surface.