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Prism dioptres. Prism correction is commonly specified in prism dioptres, a unit of angular measurement that is loosely related to the dioptre. Prism dioptres are represented by the Greek symbol delta (Δ) in superscript. A prism of power 1 Δ would produce 1 unit of displacement for an object held 100 units from the prism. [2]
Scherrer equation. The Scherrer equation, in X-ray diffraction and crystallography, is a formula that relates the size of sub- micrometre crystallites in a solid to the broadening of a peak in a diffraction pattern. It is often referred to, incorrectly, as a formula for particle size measurement or analysis. It is named after Paul Scherrer.
Relativistic corrections (Dirac) to the energy levels of a hydrogen atom from Bohr's model. The fine structure correction predicts that the Lyman-alpha line (emitted in a transition from n = 2 to n = 1) must split into a doublet. The total effect can also be obtained by using the Dirac equation. In this case, the electron is treated as non ...
The Hertz–Knudsen equation describes the non-dissociative adsorption of a gas molecule on a surface by expressing the variation of the number of molecules impacting on the surfaces per unit of time as a function of the pressure of the gas and other parameters which characterise both the gas phase molecule and the surface: [1] [2] where: Quantity.
Viscosity depends strongly on temperature. In liquids it usually decreases with increasing temperature, whereas, in most gases, viscosity increases with increasing temperature. This article discusses several models of this dependence, ranging from rigorous first-principles calculations for monatomic gases, to empirical correlations for liquids.
Fugacity. In chemical thermodynamics, the fugacity of a real gas is an effective partial pressure which replaces the mechanical partial pressure in an accurate computation of chemical equilibrium. It is equal to the pressure of an ideal gas which has the same temperature and molar Gibbs free energy as the real gas. [1]
Compressibility factor values are usually obtained by calculation from equations of state (EOS), such as the virial equation which take compound-specific empirical constants as input. For a gas that is a mixture of two or more pure gases (air or natural gas, for example), the gas composition must be known before compressibility can be calculated.
The Tolman length is thus defined as the leading order correction in an expansion in /. The equimolar radius is defined so that the superficial density is zero, i.e., it is defined by imagining a sharp mathematical dividing surface with a uniform internal and external density, but where the total mass of the pure fluid is exactly equal to the ...
In an achromatic lens, two wavelengths are brought into the same focus, here red and blue. An achromatic lens or achromat is a lens that is designed to limit the effects of chromatic and spherical aberration. Achromatic lenses are corrected to bring two wavelengths (typically red and blue) into focus on the same plane.
Eötvös rule. The Eötvös rule, named after the Hungarian physicist Loránd (Roland) Eötvös (1848–1919) enables the prediction of the surface tension of an arbitrary liquid pure substance at all temperatures. The density, molar mass and the critical temperature of the liquid have to be known. At the critical point the surface tension is zero.