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In quantum mechanics, perturbation theory is a set of approximation schemes directly related to mathematical perturbation for describing a complicated quantum system in terms of a simpler one. The idea is to start with a simple system for which a mathematical solution is known, and add an additional "perturbing" Hamiltonian representing a weak ...
Description. Perturbation theory develops an expression for the desired solution in terms of a formal power series known as a perturbation series in some "small" parameter, that quantifies the deviation from the exactly solvable problem. The leading term in this power series is the solution of the exactly solvable problem, while further terms ...
In physics, quantum tunnelling, barrier penetration, or simply tunnelling is a quantum mechanical phenomenon in which an object such as an electron or atom passes through a potential energy barrier that, according to classical mechanics, should not be passable due to the object not having sufficient energy to pass or surmount the barrier.
Planck–Einstein equation and de Broglie wavelength relations. P = ( E/c, p) is the four-momentum, K = (ω/ c, k) is the four-wavevector, E = energy of particle. ω = 2π f is the angular frequency and frequency of the particle. ħ = h /2π are the Planck constants. c = speed of light. Schrödinger equation.
In chemistry and physics, the exchange interaction is a quantum mechanical constraint on the states of indistinguishable particles. While sometimes called an exchange force, or, in the case of fermions, Pauli repulsion, its consequences cannot always be predicted based on classical ideas of force. [1] Both bosons and fermions can experience the ...
Introductory courses on physics or chemistry typically introduce the Schrödinger equation in a way that can be appreciated knowing only the concepts and notations of basic calculus, particularly derivatives with respect to space and time. A special case of the Schrödinger equation that admits a statement in those terms is the position-space ...
In physics, an effective field theory is a type of approximation, or effective theory, for an underlying physical theory, such as a quantum field theory or a statistical mechanics model. An effective field theory includes the appropriate degrees of freedom to describe physical phenomena occurring at a chosen length scale or energy scale, while ...
Dispersion (optics) In a dispersive prism, material dispersion (a wavelength -dependent refractive index) causes different colors to refract at different angles, splitting white light into a spectrum. In optics and in wave propagation in general, dispersion is the phenomenon in which the phase velocity of a wave depends on its frequency; [1 ...