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A prism of power 1 Δ would produce 1 unit of displacement for an object held 100 units from the prism. [2] Thus a prism of 1 Δ would produce 1 cm visible displacement at 100 cm, or 1 metre. This can be represented mathematically as: = where is the amount of prism correction in prism dioptres, and is the angle of deviation of the light.
Maddox wing. The Maddox Wing is an instrument utilized by ophthalmologists, orthoptists and optometrists in the measurement of strabismus (misalignment of the eyes; commonly referred to as a squint or lazy eye by the lay person). It is a quantitative and subjective method of measuring the size of a strabismic deviation by dissociation of the ...
The Benesi–Hildebrand method is a mathematical approach used in physical chemistry for the determination of the equilibrium constant K and stoichiometry of non-bonding interactions. This method has been typically applied to reaction equilibria that form one-to-one complexes, such as charge-transfer complexes and host–guest molecular ...
As the atoms of interacting molecules (or of different parts of the same molecule - intramolecular BSSE) [1] [2] approach one another, their basis functions overlap. Each monomer "borrows" functions from other nearby components, effectively increasing its basis set and improving the calculation of derived properties such as energy . [ 3 ]
The fine structure energy corrections can be obtained by using perturbation theory.To perform this calculation one must add three corrective terms to the Hamiltonian: the leading order relativistic correction to the kinetic energy, the correction due to the spin–orbit coupling, and the Darwin term coming from the quantum fluctuating motion or zitterbewegung of the electron.
The electric charge Q, third component of weak isospin T 3 (also called T z, I 3 or I z) and weak hypercharge Y W are related by = +, (or by the alternative convention Q = T 3 + Y W). The first convention, used in this article, is equivalent to the earlier Gell-Mann–Nishijima formula. It makes the hypercharge be twice the average charge of a ...
The approach is named after Max Born and his 23-year-old graduate student J. Robert Oppenheimer, the latter of whom proposed it in 1927 during a period of intense fervent in the development of quantum mechanics. [2][3] The approximation is widely used in quantum chemistry to speed up the computation of molecular wavefunctions and other ...
Collision theory. Reaction rate tends to increase with concentration phenomenon explained by collision theory. Collision theory is a principle of chemistry used to predict the rates of chemical reactions. It states that when suitable particles of the reactant hit each other with the correct orientation, only a certain amount of collisions ...