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The Edwards equation in organic chemistry is a two-parameter equation for correlating nucleophilic reactivity, as defined by relative rate constants, with the basicity of the nucleophile (relative to protons) and its polarizability. This equation was first developed by John O. Edwards in 1954 [1] and later revised based on additional work in 1956.
Prism dioptres. Prism correction is commonly specified in prism dioptres, a unit of angular measurement that is loosely related to the dioptre. Prism dioptres are represented by the Greek symbol delta (Δ) in superscript. A prism of power 1 Δ would produce 1 unit of displacement for an object held 100 units from the prism. [2]
The Benesi–Hildebrand method is a mathematical approach used in physical chemistry for the determination of the equilibrium constant K and stoichiometry of non-bonding interactions. This method has been typically applied to reaction equilibria that form one-to-one complexes, such as charge-transfer complexes and host–guest molecular ...
Relativistic corrections (Dirac) to the energy levels of a hydrogen atom from Bohr's model. The fine structure correction predicts that the Lyman-alpha line (emitted in a transition from n = 2 to n = 1) must split into a doublet. The total effect can also be obtained by using the Dirac equation. In this case, the electron is treated as non ...
Square antiprism. In geometry, the square antiprism is the second in an infinite family of antiprisms formed by an even-numbered sequence of triangle sides closed by two polygon caps. It is also known as an anticube. [1] If all its faces are regular, it is a semiregular polyhedron or uniform polyhedron .
Unit cell with water molecules, used to simulate flowing water. Periodic boundary conditions (PBCs) are a set of boundary conditions which are often chosen for approximating a large (infinite) system by using a small part called a unit cell. PBCs are often used in computer simulations and mathematical models. The topology of two-dimensional PBC ...
Maddox wing. The Maddox Wing is an instrument utilized by ophthalmologists, orthoptists and optometrists in the measurement of strabismus (misalignment of the eyes; commonly referred to as a squint or lazy eye by the lay person). It is a quantitative and subjective method of measuring the size of a strabismic deviation by dissociation of the ...
Thermal desorption is described by the Polanyi–Wigner equation derived from the Arrhenius equation . where. the desorption rate [mol/ (cm 2 s)] as a function of , order of desorption, surface coverage, pre-exponential factor [Hz] as a function of , activation energy of desorption [kJ/mol] as a function of , gas constant [J/ (K mol ...