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  2. Prism correction - Wikipedia

    en.wikipedia.org/wiki/Prism_correction

    Prism dioptres. Prism correction is commonly specified in prism dioptres, a unit of angular measurement that is loosely related to the dioptre. Prism dioptres are represented by the Greek symbol delta (Δ) in superscript. A prism of power 1 Δ would produce 1 unit of displacement for an object held 100 units from the prism. [2]

  3. Benesi–Hildebrand method - Wikipedia

    en.wikipedia.org/wiki/Benesi–Hildebrand_method

    The Benesi–Hildebrand method is a mathematical approach used in physical chemistry for the determination of the equilibrium constant K and stoichiometry of non-bonding interactions. This method has been typically applied to reaction equilibria that form one-to-one complexes, such as charge-transfer complexes and host–guest molecular ...

  4. Eyring equation - Wikipedia

    en.wikipedia.org/wiki/Eyring_equation

    The Eyring equation (occasionally also known as Eyring–Polanyi equation) is an equation used in chemical kinetics to describe changes in the rate of a chemical reaction against temperature. It was developed almost simultaneously in 1935 by Henry Eyring, Meredith Gwynne Evans and Michael Polanyi. The equation follows from the transition state ...

  5. Fine structure - Wikipedia

    en.wikipedia.org/wiki/Fine_structure

    The fine structure energy corrections can be obtained by using perturbation theory.To perform this calculation one must add three corrective terms to the Hamiltonian: the leading order relativistic correction to the kinetic energy, the correction due to the spin–orbit coupling, and the Darwin term coming from the quantum fluctuating motion or zitterbewegung of the electron.

  6. Effective medium approximations - Wikipedia

    en.wikipedia.org/wiki/Effective_medium...

    Effective medium approximations. In materials science, effective medium approximations (EMA) or effective medium theory (EMT) pertain to analytical or theoretical modeling that describes the macroscopic properties of composite materials. EMAs or EMTs are developed from averaging the multiple values of the constituents that directly make up the ...

  7. Cauchy's equation - Wikipedia

    en.wikipedia.org/wiki/Cauchy's_equation

    It deviates in the ultraviolet and infrared regions. In optics, Cauchy's transmission equation is an empirical relationship between the refractive index and wavelength of light for a particular transparent material. It is named for the mathematician Augustin-Louis Cauchy, who originally defined it in 1830 in his article "The refraction and ...

  8. UNIFAC - Wikipedia

    en.wikipedia.org/wiki/UNIFAC

    Image is rotating to more clearly show the saddle-like shape of the vapor–liquid equilibria. In statistical thermodynamics, the UNIFAC method (UNI QUAC F unctional-group A ctivity C oefficients) [1] is a semi-empirical system for the prediction of non-electrolyte activity in non- ideal mixtures. UNIFAC uses the functional groups present on ...

  9. Bohr–Sommerfeld model - Wikipedia

    en.wikipedia.org/wiki/Bohr–Sommerfeld_model

    The Bohr–Sommerfeld model (also known as the Sommerfeld model or Bohr–Sommerfeld theory) was an extension of the Bohr model to allow elliptical orbits of electrons around an atomic nucleus. Bohr–Sommerfeld theory is named after Danish physicist Niels Bohr and German physicist Arnold Sommerfeld. Sommerfeld argued that if electronic orbits ...