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In quantum mechanics, perturbation theory is a set of approximation schemes directly related to mathematical perturbation for describing a complicated quantum system in terms of a simpler one. The idea is to start with a simple system for which a mathematical solution is known, and add an additional "perturbing" Hamiltonian representing a weak ...
Variational method (quantum mechanics) In quantum mechanics, the variational method is one way of finding approximations to the lowest energy eigenstate or ground state, and some excited states. This allows calculating approximate wavefunctions such as molecular orbitals. [1] The basis for this method is the variational principle.
t. e. The GW approximation (GWA) is an approximation made in order to calculate the self-energy of a many-body system of electrons. [1] [2] [3] The approximation is that the expansion of the self-energy Σ in terms of the single particle Green's function G and the screened Coulomb interaction W (in units of ) can be truncated after the first term:
Prism dioptres. Prism correction is commonly specified in prism dioptres, a unit of angular measurement that is loosely related to the dioptre. Prism dioptres are represented by the Greek symbol delta (Δ) in superscript. A prism of power 1 Δ would produce 1 unit of displacement for an object held 100 units from the prism. [2]
Fine structure. Interference fringes, showing fine structure (splitting) of a cooled deuterium source, viewed through a Fabry–Pérot interferometer. In atomic physics, the fine structure describes the splitting of the spectral lines of atoms due to electron spin and relativistic corrections to the non-relativistic Schrödinger equation.
In quantum mechanics, an energy level is degenerate if it corresponds to two or more different measurable states of a quantum system. Conversely, two or more different states of a quantum mechanical system are said to be degenerate if they give the same value of energy upon measurement. The number of different states corresponding to a ...
Eyring equation. The Eyring equation (occasionally also known as Eyring–Polanyi equation) is an equation used in chemical kinetics to describe changes in the rate of a chemical reaction against temperature. It was developed almost simultaneously in 1935 by Henry Eyring, Meredith Gwynne Evans and Michael Polanyi.
Esophoria is an eye condition involving inward deviation of the eye, usually due to extra-ocular muscle imbalance. It is a type of heterophoria. Cause. Causes include: Refractive errors; Divergence insufficiency; Convergence excess; this can be due to nerve, muscle, congenital or mechanical anomalies.
In a prism, the angle of deviation (δ) decreases with increase in the angle of incidence (i) up to a particular angle.This angle of incidence where the angle of deviation in a prism is minimum is called the minimum deviation position of the prism and that very deviation angle is known as the minimum angle of deviation (denoted by δ min, D λ, or D m).
Specific rotation. In chemistry, specific rotation ( [α]) is a property of a chiral chemical compound. [1] : 244 It is defined as the change in orientation of monochromatic plane-polarized light, per unit distance–concentration product, as the light passes through a sample of a compound in solution. [2] : 2–65 Compounds which rotate the ...