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In quantum mechanics, perturbation theory is a set of approximation schemes directly related to mathematical perturbation for describing a complicated quantum system in terms of a simpler one. The idea is to start with a simple system for which a mathematical solution is known, and add an additional "perturbing" Hamiltonian representing a weak ...
Fine structure. Interference fringes, showing fine structure (splitting) of a cooled deuterium source, viewed through a Fabry–Pérot interferometer. In atomic physics, the fine structure describes the splitting of the spectral lines of atoms due to electron spin and relativistic corrections to the non-relativistic Schrödinger equation.
Prism dioptres. Prism correction is commonly specified in prism dioptres, a unit of angular measurement that is loosely related to the dioptre. Prism dioptres are represented by the Greek symbol delta (Δ) in superscript. A prism of power 1 Δ would produce 1 unit of displacement for an object held 100 units from the prism. [2]
Using the Euler–Lagrange equation for the field, ∂ ν ( ∂ L ∂ ( ∂ ν A μ ) ) − ∂ L ∂ A μ = 0 , {\displaystyle \partial _{ u }\left({\frac {\partial {\mathcal {L}}}{\partial (\partial _{ u }A_{\mu })}}\right)-{\frac {\partial {\mathcal {L}}}{\partial A_{\mu }}}=0,}
Planck–Einstein equation and de Broglie wavelength relations. P = ( E/c, p) is the four-momentum, K = (ω/ c, k) is the four-wavevector, E = energy of particle. ω = 2π f is the angular frequency and frequency of the particle. ħ = h /2π are the Planck constants. c = speed of light. Schrödinger equation.
The Schrödinger equation is a linear differential equation, meaning that if two state vectors and are solutions, then so is any linear combination. of the two state vectors where a and b are any complex numbers. [13] : 25 Moreover, the sum can be extended for any number of state vectors.
Introduction to the concept. Quantum tunnelling falls under the domain of quantum mechanics. To understand the phenomenon, particles attempting to travel across a potential barrier can be compared to a ball trying to roll over a hill. Quantum mechanics and classical mechanics differ in their treatment of this scenario.
In quantum chemistry and molecular physics, the Born–Oppenheimer ( BO) approximation is the best-known mathematical approximation in molecular dynamics. Specifically, it is the assumption that the wave functions of atomic nuclei and electrons in a molecule can be treated separately, based on the fact that the nuclei are much heavier than the ...
In physics, relativistic quantum mechanics ( RQM) is any Poincaré covariant formulation of quantum mechanics (QM). This theory is applicable to massive particles propagating at all velocities up to those comparable to the speed of light c, and can accommodate massless particles. The theory has application in high energy physics, [1] particle ...
Marcus theory is used to describe a number of important processes in chemistry and biology, including photosynthesis, corrosion, certain types of chemiluminescence, charge separation in some types of solar cells and more. Besides the inner and outer sphere applications, Marcus theory has been extended to address heterogeneous electron transfer .