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Thus a prism of 1 Δ would produce 1 cm visible displacement at 100 cm, or 1 meter. This can be represented mathematically as: = where is the amount of prism correction in prism dioptres, and is the angle of deviation of the light.
Goldman's equation seeks to determine the voltage E m across a membrane. A Cartesian coordinate system is used to describe the system, with the z direction being perpendicular to the membrane.
This can be described by the following equation: [ HG ] = [ H ] 0 K a [ G ] 1 + K a [ G ] {\displaystyle [{\ce {HG}}]={\frac {[{\ce {H}}]_{0}K_{\rm {a}}[{\ce {G}}]}{1+K_{\rm {a}}[{\ce {G}}]}}} By substituting the binding isotherm equation into the previous equation, the equilibrium constant K a can now be correlated to the change in absorbance ...
Relativistic corrections (Dirac) to the energy levels of a hydrogen atom from Bohr's model. The fine structure correction predicts that the Lyman-alpha line (emitted in a transition from n = 2 to n = 1) must split into a doublet. The total effect can also be obtained by using the Dirac equation. In this case, the electron is treated as non ...
The Scherrer equation, in X-ray diffraction and crystallography, is a formula that relates the size of sub-micrometre crystallites in a solid to the broadening of a peak in a diffraction pattern. It is often referred to, incorrectly, as a formula for particle size measurement or analysis.
Viscosity depends strongly on temperature. In liquids it usually decreases with increasing temperature, whereas, in most gases, viscosity increases with increasing temperature. This article discusses several models of this dependence, ranging from rigorous first-principles calculations for monatomic gases, to empirical correlations for liquids.
The result for two conducting spheres in a solvent is the formula of Marcus G = ( 1 2 r 1 + 1 2 r 2 − 1 R ) ⋅ ( 1 ϵ opt − 1 ϵ s ) ⋅ ( Δ e ) 2 {\displaystyle G=\left({\frac {1}{2r_{1}}}+{\frac {1}{2r_{2}}}-{\frac {1}{R}}\right)\cdot \left({\frac {1}{\epsilon _{\text{opt}}}}-{\frac {1}{\epsilon _{\text{s}}}}\right)\cdot (\Delta e)^{2}}
Antoine equation. The Antoine equation is a class of semi-empirical correlations describing the relation between vapor pressure and temperature for pure substances. The Antoine equation is derived from the Clausius–Clapeyron relation. The equation was presented in 1888 by the French engineer Louis Charles Antoine [ fr] (1825–1897).
Gross–Pitaevskii equation. The Gross–Pitaevskii equation ( GPE, named after Eugene P. Gross [1] and Lev Petrovich Pitaevskii [2]) describes the ground state of a quantum system of identical bosons using the Hartree–Fock approximation and the pseudopotential interaction model. A Bose–Einstein condensate (BEC) is a gas of bosons that are ...
The Bohr–Sommerfeld model (also known as the Sommerfeld model or Bohr–Sommerfeld theory) was an extension of the Bohr model to allow elliptical orbits of electrons around an atomic nucleus. Bohr–Sommerfeld theory is named after Danish physicist Niels Bohr and German physicist Arnold Sommerfeld. Sommerfeld argued that if electronic orbits ...