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Prism dioptres. Prism correction is commonly specified in prism dioptres, a unit of angular measurement that is loosely related to the dioptre. Prism dioptres are represented by the Greek symbol delta (Δ) in superscript. A prism of power 1 Δ would produce 1 unit of displacement for an object held 100 units from the prism. [2]
In quantum mechanics, perturbation theory is a set of approximation schemes directly related to mathematical perturbation for describing a complicated quantum system in terms of a simpler one. The idea is to start with a simple system for which a mathematical solution is known, and add an additional "perturbing" Hamiltonian representing a weak ...
Fine structure. Interference fringes, showing fine structure (splitting) of a cooled deuterium source, viewed through a Fabry–Pérot interferometer. In atomic physics, the fine structure describes the splitting of the spectral lines of atoms due to electron spin and relativistic corrections to the non-relativistic Schrödinger equation.
Periodic boundary conditions. Periodic boundary conditions (PBCs) are a set of boundary conditions which are often chosen for approximating a large (infinite) system by using a small part called a unit cell. PBCs are often used in computer simulations and mathematical models. The topology of two-dimensional PBC is equal to that of a world map ...
e. In particle physics, quantum electrodynamics ( QED) is the relativistic quantum field theory of electrodynamics. [1] [2] [3] In essence, it describes how light and matter interact and is the first theory where full agreement between quantum mechanics and special relativity is achieved. [2]
Density matrix renormalization group. The density matrix renormalization group ( DMRG) is a numerical variational technique devised to obtain the low-energy physics of quantum many-body systems with high accuracy. As a variational method, DMRG is an efficient algorithm that attempts to find the lowest-energy matrix product state wavefunction of ...
Atomic absorption spectroscopy ( AAS) and atomic emission spectroscopy ( AES) is a spectroanalytical procedure for the quantitative determination of chemical elements by free atoms in the gaseous state. Atomic absorption spectroscopy is based on absorption of light by free metallic ions. In analytical chemistry the technique is used for ...
Spin contamination. In computational chemistry, spin contamination is the artificial mixing of different electronic spin -states. This can occur when an approximate orbital-based wave function is represented in an unrestricted form – that is, when the spatial parts of α and β spin-orbitals are permitted to differ.
Applications. There are many different effective medium approximations, each of them being more or less accurate in distinct conditions. Nevertheless, they all assume that the macroscopic system is homogeneous and, typical of all mean field theories, they fail to predict the properties of a multiphase medium close to the percolation threshold due to the absence of long-range correlations or ...
Whereas in the CHA model, those orbitals have no greater intrinsic freedom and therefore the correction treats all fragments equally. The errors inherent in either BSSE correction disappear more rapidly than the total value of BSSE in larger basis sets. See also. Basis set (chemistry) Quantum chemistry; Quantum chemistry computer programs